PHYSICAL AND CHEMICAL STRUCTURE ANALYSIS FOR THE COMPOSITION OF MATERIALS: FROM CHEMISTRY DISORDER TO THERMODYNAMICS OF UNBALANCED STRUCTURES

KHEIFETZ Mikhail L., D. Sc. in Eng., Prof., Deputy Academician-Secretary, Chief Researcher, Presidium of the National Academy of Sciences of Belarus, Minsk, Republic of Belarus, OJSC “NPO Center”, Minsk, Republic of Belarus, This email address is being protected from spambots. You need JavaScript enabled to view it.">This email address is being protected from spambots. You need JavaScript enabled to view it.

KOLMAKOV Aleksei G., Corresponding Member of the RAS, D. Sc. in Eng., Deputy Director for Research, A.A. Baikov Institute of Metallurgy and Materials Science of the Russian Academy of Sciences, Moscow, Russia, This email address is being protected from spambots. You need JavaScript enabled to view it.">This email address is being protected from spambots. You need JavaScript enabled to view it.

KLIMENKO Sergei A., D. Sc. in Eng., Prof., Deputy Director for Research, V. Bakul Institute for Superhard Materials of the National Academy of Sciences of Ukraine, Kiev, Ukraine, This email address is being protected from spambots. You need JavaScript enabled to view it.">This email address is being protected from spambots. You need JavaScript enabled to view it.

The stages of the development of the physicochemical foundations of materials science are revealed, and the state and prospects of the development of nanostructured material science based on a comprehensive study of the structure of matter at various scale levels are determined. The use of complex analysis of the formation of material structures is characterized by traditional for chemistry and physics study of the balance of matter and energy flows, supplemented by an analysis of entropy formation and by physical and chemical analysis of combinatorial topology used to describe non-equilibrium phase transitions as well as by based on the synergetic approach percolation representations of fractal geometry, used to describe a complex of structures. It is shown that for the study of non-equilibrium processes of synthesis and application of micro- and nanostructured materials it is expedient to supplement the principles of physicochemical analysis: continuity principle — by considering additionally energy dissipation in the formation of structures and phases; correspondence principle — by fractal representations of geometric images; compatibility principle — by the study of possible ways of evolution of the system. This allows quantitative analyzing of transient processes described by non-integer values of the degrees of freedom of the system and the emerging structures with multi-fractal phase parameters.

physicochemical structural analysis, chemical disorder of matter, non-equilibrium thermodynamics of processes, synergetic approach, multifractal parameters, nanostructured material

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