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Title of the article INFLUENCE OF THE STRUCTURE OF IRON-TITANIUM THERMAL SPRAYED COATINGS ON THEIR WEAR RESISTANCE
Authors

KUKAREKO Vladimir A., D. Sc. in Phys. and Math., Prof., Chief of the Center of Structural Research and Tribomechanical Testing of Materials and Mechanical Engineering Products of Collective Use of the R&D Center “Mechanical Engineering Technologies and Processing Equipment”, Joint Institute of Mechanical Engineering of the NAS of Belarus, Minsk, Republic of Belarus, This email address is being protected from spambots. You need JavaScript enabled to view it.">This email address is being protected from spambots. You need JavaScript enabled to view it.

BELOTSERKOVSKY Marat А., D. Sc. in Eng., Prof., Head of the Laboratory of Gas-Thermal Methods of Machine Components Hardening of the R&D Center “Mechanical Engineering Technologies and Processing Equipment”, Joint Institute of Mechanical Engineering of the NAS of Belarus, Minsk, Republic of Belarus, This email address is being protected from spambots. You need JavaScript enabled to view it.">This email address is being protected from spambots. You need JavaScript enabled to view it.

GRIGORCHIK Alexander N., Ph. D. in Eng., Deputy Head of the Center of Structural Research and Tribomechanical Testing of Materials and Mechanical Engineering Products of Collective Use of the R&D Center “Mechanical Engineering Technologies and Processing Equipment”, Joint Institute of Mechanical Engineering of the NAS of Belarus, Minsk, Republic of Belarus, This email address is being protected from spambots. You need JavaScript enabled to view it.">This email address is being protected from spambots. You need JavaScript enabled to view it.

SOSNOVSKIY Aleksey V., Ph. D. in Eng., Leading Researcher of the Laboratory of Gas-Thermal Methods of Machine Component Hardening of the R&D Center “Mechanical Engineering Technologies and Processing Equipment”, Joint Institute of Mechanical Engineering of the NAS of Belarus, Minsk, Republic of Belarus, This email address is being protected from spambots. You need JavaScript enabled to view it.">This email address is being protected from spambots. You need JavaScript enabled to view it.

In the section MATERIALS SCIENCE IN MECHANICAL ENGINEERING
Year 2023
Issue 1(62)
Pages 72–78
Type of article RAR
Index UDK 621.793
DOI https://doi.org/10.46864/1995-0470-2023-1-62-72-78
Abstract The paper studies the structure, phase composition and properties of thermal sprayed coatings made of Ti4Al titanium alloy and “Ti4Al + AISI420” pseudoalloy obtained by hypersonic metallization. It is shown that the deposited coatings include in the phase composition a large amount of titanium nitride TiN (up to 70 vol.%), which is formed during the metallization process. At the same time, an increase in propane pressure during metallization from 0.3 to 0.4 MPa leads to a slight decrease in the titanium nitride content in the sprayed coating. It is associated with an increase in the flight velocity of molten titanium droplets in an atmosphere of ionized gases and, accordingly, a decrease in the time of their interaction with ionized air nitrogen atoms. The porosity of the sprayed coatings made of titanium alloy Ti4Al is 30–35 vol.%, and their hardness and microhardness are 500–650 HV 1 and 1,300–1,600 HV 0.1, respectively. Coatings made of “Ti4Al + AISI420” pseudoalloy have a reduced porosity of 10–15 vol.%, and their hardness and microhardness are 500–600 HV 1 and 900–1,300 HV 0.1, respectively. It is shown that coatings made of Ti4Al alloy and “Ti4Al + AISI420” pseudoalloy are characterized by increased wear resistance under friction without lubricant. In particular, the intensity of mass wear of coatings Iq made of Ti4Al titanium alloy, obtained at propane pressures of 0.3 and 0.4 MPa, is 2.5–2.6×10–3 mg/m, and Iq for coatings made of “Ti4Al + AISI420” pseudoalloy is 1.0–1.1×10–3 mg/m. The reduced values of mass wear intensities of coatings made of “Ti4Al + AISI420” pseudoalloy are associated with the presence of TiN in them and relatively low porosity.
Keywords hypersonic metallization, titanium alloy, titanium nitride, porosity, microhardness, wear resistance
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Bibliography
  1. Belotserkovsky M.A., Sosnovskiy A.V., Pryadko A.S., Yalovik A.P., Trusov D.I. Vybor tekhnologicheskikh parametrov protsessa naneseniya stalnykh pokrytiy metodom giperzvukovoy metallizatsii [Selecting the technological parameters of steel coatings formation by hypersonic metallization]. Mechanics of machines, mechanisms and materials, 2015, no. 3(32), pp. 52–57 (in Russ.).
  2. Ilyushchenko A.F., Shevtsov A.I., Okovityy V.A., Gromyko G.F. Protsessy formirovaniya gazotermicheskikh pokrytiy i ikh modelirovanie [Processes of formation of thermal sprayed coatings and their modeling]. Minsk, Belorusskaya nauka Publ., 2011. 357 p. (in Russ.).
  3. Kukareko V.A., Belotserkovsky M.A., Grigorchik A.N., Astrashab E.V., Sosnovsky A.V. Strukturno-fazovoe sostoyanie i tribotekhnicheskie svoystva psevdosplavov, napylennykh iz vysokokhromistykh staley i tsvetnykh metallov [Structural-phase state and tribological properties of pseudoalloys deposited from high-chromium steels and non-ferrous metals]. Strengthening technologies and coatings, 2019, vol. 15, no. 8(176), pp. 355–359 (in Russ.).
  4. Sorokov I.O., Spiridonov N.V., Neroda M.V. Tekhnologiya uprochneniya tyazhelonagruzhennykh detaley gazotermicheskim napyleniem [Technology of hardening of heavy-loaded parts by gas-thermal spraying]. Baranovichi, RIO BarGU Publ., 2012. 183 p. (in Russ.).
  5. Korzhik V.N., Borisova A.L., Gordan G.N., Liutik N.P., Chaika A.A., Kajda T.V. Osobennosti struktury pokrytiy iz poroshkovoy provoloki sistemy Fe-Cr-Al, poluchennykh v usloviyakh sverkhzvukovoy elektrodugovoy metallizatsii [Peculiarities of structure of coatings of Fe-Cr-Al system flux-cored wire produced under the conditions of supersonic electric arc metallization]. Automatic welding, 2014, no. 2(729), pp. 33–38 (in Russ.).
  6. Astrashab E.V., Grigorchik A.N., Kukareko V.A., Belotserkovsky M.A. Vliyanie temperatury i vremeni otzhiga na iznosostoykost pokrytiy iz psevdosplava na osnove Ni-Cr-Al, napylennykh metodom vysokoskorostnoy metallizatsii [Effect of temperature and time of annealing on the wear resistance of Ni-Cr-Al-based pseudo-alloy coatings deposited by high-speed metallization]. Trenie i iznos, 2020, vol. 41, no. 5, pp. 538–544 (in Russ.).
  7. Rusakov V.S., Kadyrzhanov K.K., Suslov E.E., Plaksin D.A., Turkebaev T.E. Termicheski indutsirovannye fazovye preobrazovaniya v sloistoy sisteme Fe-Al [Thermally induced phase transformations in layered Fe-Al system]. Poverkhnost. Rentgenovskie, sinkhrotronnye i neytronnye issledovaniya, 2004, no. 12, pp. 22–30 (in Russ.).
  8. Hasui A., Morigaki O. Naplavka i napylenie [Surfacing and spraying]. Moscow, Mashinostroenie Publ., 1985. 240 p. (in Russ.).
  9. Wang H.-T., Li C.-J., Yang G.-J., Li C.-X. Cold spraying of Fe/Al powder mixture: Coating characteristics and influence of heat treatment on the phase structure. Applied surface science, 2008, vol. 255, iss. 5, part 1, pp. 2538–2544. DOI: https://doi.org/10.1016/j.apsusc.2008.07.127.
  10. Senderowski C., Bojar Z., Wołczyński W., Pawłowski A. Microstructure characterization of D-gun sprayed Fe-Al intermetallic coatings. Intermetallics, 2010, vol. 18, iss. 7, pp. 1405–1409. DOI: https://doi.org/10.1016/j.intermet.2010.01.015.
  11. Liu S.-G., Wu J.-M., Zhang S.-C., Rong S.-J., Li Z.-Z. High temperature erosion properties of arc-sprayed coatings using various cored wires containing Ti-Al intermetallics. Wear, 2007, vol. 262, iss. 5–6, pp. 555–561. DOI: https://doi.org/10.1016/j.wear.2006.06.021.
  12. Panas A.J., Senderowski C., Fikus B. Thermophysical properties of multiphase Fe-Al intermetallic-oxide ceramic coatings deposited by gas detonation spraying. Thermochimica acta, 2019, vol. 676, pp. 164–171. DOI: https://doi.org/10.1016/j.tca.2019.04.009.
  13. Bataev I.A., Bataev A.A., Pavlyukova D.V., Yartsev P.S., Golovin E.D., Mali V.I. Zarozhdenie i rost alyuminida titana v sloistom kompozite, svarennom vzryvom [Nucleation and growth of titanium aluminide in an explosion welded laminate composite]. Fizika metallov i materialovedenie, 2012, vol. 113, no. 10, pp. 998–1007 (in Russ.).
  14. Pezzutti M.D., Ajdelsztajn L. Cold spray repair of engine components. Patent US, no. 20210017651 A1, 2021.
  15. Samsonov G.V., Kulik O.P., Polishchuk V.S. Poluchenie i metody analiza nitridov [Production and methods of analysis of nitrides]. Kiev, Nauchnaya mysl Pybl., 1978. 320 p. (in Russ.).