Title of the article

MECHANICAL ACTIVATION OF THE POWDER MIXTURE OF “ULTRA-HIGH MOLECULAR WEIGHT POLYETHYLENE — COMPOSITE B4C/W”

Authors

KOVALEVA Svetlana A., Senior Researcher of the Laboratory of Nanostructured and Superhard Materials, Joint Institute of Mechanical Engineering of the NAS of Belarus, Minsk, Republic of Belarus, This email address is being protected from spambots. You need JavaScript enabled to view it.">This email address is being protected from spambots. You need JavaScript enabled to view it.

ZHORNIK Viktor I., D. Sc. in Eng., Assoc. Prof., Head of the Laboratory of Nanostructured and Superhard Materials, Joint Institute of Mechanical Engineering of the NAS of Belarus, Minsk, Republic of Belarus, This email address is being protected from spambots. You need JavaScript enabled to view it.">This email address is being protected from spambots. You need JavaScript enabled to view it.

GRIGORIEVA Tatyana F., D. Sc. in Chem., Leading Researcher of the Laboratory of Chemical Materials Science, Solid State Chemistry and Mechanochemistry of the Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia

In the section MATERIALS SCIENCE IN MECHANICAL ENGINEERING
Year 2018 Issue 4 Pages 65–71
Type of article RAR Index UDK 621.762.2 Index BBK  
Abstract

The article presents the results of the experimental studies of the structural transformations of a powder mixture of ultra-high molecular weight polyethylene and 80 wt.% (45 vol.%) of the nanostructured composite B4C/W treated in a high-energy ball planetary mill that are studied by the methods of X-ray diffraction, scanning electron microscopy and Fourier-IR spectroscopy. It is shown that the polymer composite particles of a flaky shape and the size of 160–400 μm with a uniform distribution in them of boron carbide and tungsten particles with the size of 1–5  μm and 0.1–0.2 μm respectively are formed during the process of mechanical activation (MA), while the oxidative destruction of polymer is not detected. The main results of the interaction of the polymer matrix and dispersed filler powders with MA are the processes of breaking of intramolecular bonds, cross-linking of polymer molecules, as well as mechanical dispersion of particles.

Keywords

mechanical activation, microstructure, composites, ultra-high molecular weight polyethylene, boron carbide, tungsten

   
Bibliography
  • Senatov F.S., Senatova S.I., Gorshenkov M.V., Cherdyntsev V.V. Struktura plenok SVMPE posle oblucheniya uskorennymi tyazhelymi ionami [Structure of UHMWPE films after irradiation with heavy ions]. Sovremennye problemy nauki i obrazovaniya [Modern problems of science and education], 2013, no. 5. Available at: http://science-education.ru/ru/article/view?id=10046.
  • Okhlopkova A.A., Petrova P.N., Popov S.N., Sleptsova S.A. Polimernye kompozitsionnye materialy tribotekhnicheskogo naznacheniya na osnove politetraftoretilena [Polymer composite materials of tribotechnical purpose based on polytetrafluoroethylene]. Rossiyskiy khimicheskiy zhurnal [Russian chemical journal], 2008, vol. 52, no. 3, pp. 147–152.
  • Shteynberk E.M., Zenitova L.A. Snizhenie ekologocheskoy opasnosti radiatsionnogo oblucheniya s ispolzovaniem polimernykh kompozitsionnykh materialov. Obzor [Reducing the environmental risk of radiation exposure using polymer composite materials. Review]. Vestnik Kazanskogo tekhnologicheskogo universiteta [Herald of Kazan Technological University], 2012, no. 15(8), pp. 67–71.
  • Ancharov A.I., et. al. Mekhanokompozity — prekursory dlya sozdaniya materialov s novymi svoystvami [Mechanocomposites — precursors for creating materials with new properties]. Novosibirsk, Izdatelstvo SO RAN Publ., 2010. 424 p.
  • Wannasri S., Panina S.V., Ivanova L.R., Kornienko L.A., Piriyayona S. Increasing wear resistance of UHMWPE by mechanical activation and chemical modification combined with addition of nanofibers. Procedia Engineering, 2009, no. 1, pp. 67–70.
  • Borunova A.B., Zhernovenkova Yu.V., Streletskiy A.N., Portnoy V.K. Opredelenie energonapryazhennosti mekhanoaktivatorov razlichnogo tipa [Determination of the energy intensity of different types of mechanical activators]. Obrabotka dispersnykh materialov i sred [Processing of dispersed materials and media], 1999, issue 9, pp. 158–163.
  • Domnich V., Reynaud S., Haber R.A., Chhowalla M. Boron Carbide: Structure, Properties, and Stability under Stress. Journal of the American Ceramic Society, 2011, no. 94(11), pp.   3605–3628.
  • Lifshits E.V., Shevyakova E.P., Ostapenko I.T., Bereznyak E.P., Saenko L.A. IK-spektroskopiya karbidov bora razlichnoy stekhiometrii [IR-spectroscopy of the different stoichiometry boron carbides]. Voprosy atomnoy nauki i tekhniki. Seriya: Fizika radiatsionnykh povrezhdeniy i radiatsionnoe materialovedenie [Problems of atomic science and technology. Series: Physics of radiation effect and radiation materials science], 2004, no. 3(85), pp. 19–22.
  • Edidin A.A., Jewett C.W., Kwarteng K., Kalinowski A., Kurtz  S.M. Degradation of mechanical behavior in UHMWPE after natural and accelerated aging. Biomaterials, 2000, vol. 21, pp. 1451–1460.
  • Dechant J., Danz R., Kimmer W., Schmolke R. Ultrarotspektroskopische Untersuchungen an Polymeren. Berlin, Akademie Publ., 1972.