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Title of the article STRUCTURE AND PROPERTIES OF POWDER MATERIALS BASED ON MECHANOSYNTHESIZED METAL MATRIX COMPOSITES Ni-TiC
Authors

KOVALIOVA Svetlana A., Ph. D. in Eng., Assoc. Prof., Leading Researcher of the Laboratory of Nanostructured and Superhard Materials of the R&D Center “Mechanical Engineering Technologies and Processing Equipment”, Joint Institute of Mechanical Engineering of the NAS of Belarus, Minsk, Republic of Belarus, This email address is being protected from spambots. You need JavaScript enabled to view it.">This email address is being protected from spambots. You need JavaScript enabled to view it.

ZHORNIK Viktor I., D. Sc. in Eng., Prof., Head of the Department of Mechanical Engineering and Metallurgy of the R&D Center “Mechanical Engineering Technologies and Processing Equipment” – Head of the Laboratory of Nanostructured and Superhard Materials, Joint Institute of Mechanical Engineering of the NAS of Belarus, Minsk, Republic of Belarus, This email address is being protected from spambots. You need JavaScript enabled to view it.">This email address is being protected from spambots. You need JavaScript enabled to view it.

VITYAZ Pyotr A., Academician of the NAS of Belarus, D. Sc. in Eng., Prof., Chief Researcher of the Laboratory of Nanostructured and Superhard Materials of the R&D Center “Mechanical Engineering Technologies and Processing Equipment”, Joint Institute of Mechanical Engineering of the NAS of Belarus, Minsk, Republic of Belarus, This email address is being protected from spambots. You need JavaScript enabled to view it.">This email address is being protected from spambots. You need JavaScript enabled to view it.

GRIGOREVA Tatiana F., D. Sc. in Chem., Leading Researcher of the Laboratory of Chemical Materials Science, Institute of Solid State Chemistry and Mechanochemistry of the Siberian Branch of the RAS, Novosibirsk, Russian Federation, This email address is being protected from spambots. You need JavaScript enabled to view it.">This email address is being protected from spambots. You need JavaScript enabled to view it.

DUDINA Dina V., D. Sc. in Eng., Senior Researcher of the Laboratory of Chemical Materials Science, Institute of Solid State Chemistry and Mechanochemistry of the Siberian Branch of the RAS, Novosibirsk, Russian Federation; Leading Researcher of the Laboratory for the Synthesis of Composite Materials, M.A. Lavrentiev Institute of Hydrodynamics of the Siberian Branch of the RAS, Novosibirsk, Russian Federation,
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UKHINA Arina V., Ph. D. in Chem., Senior Researcher of the Laboratory of Solid State Ionics, Institute of Solid State Chemistry and Mechanochemistry of the Siberian Branch of the RAS, Novosibirsk, Russian Federation, This email address is being protected from spambots. You need JavaScript enabled to view it.">This email address is being protected from spambots. You need JavaScript enabled to view it.

VIDYUK Tomila M., Ph. D. in Chem., Researcher of the Laboratory of Chemical Materials Science, Institute of Solid State Chemistry and Mechanochemistry of the Siberian Branch of the RAS, Novosibirsk, Russian Federation; Junior Researcher of the Laboratory of Physics of Multiphase Media, Khristianovich Institute of Theoretical and Applied Mechanics of the Siberian Branch of the RAS, Novosibirsk, Russian Federation, This email address is being protected from spambots. You need JavaScript enabled to view it.">This email address is being protected from spambots. You need JavaScript enabled to view it.

VOSMERIKOV Sergey V., Researcher of the Laboratory of Chemical Materials Science, Institute of Solid State Chemistry and Mechanochemistry of the Siberian Branch of the RAS, Novosibirsk, Russian Federation, This email address is being protected from spambots. You need JavaScript enabled to view it.">This email address is being protected from spambots. You need JavaScript enabled to view it.

DEVYATKINA Evgeniya T., Researcher of the Laboratory of Chemical Materials Science, Institute of Solid State Chemistry and Mechanochemistry of the Siberian Branch of the RAS, Novosibirsk, Russian Federation, This email address is being protected from spambots. You need JavaScript enabled to view it.">This email address is being protected from spambots. You need JavaScript enabled to view it.

LYAKHOV Nikolay Z., Academician of the RAS, D. Sc. in Chem., Prof., Scientific Director of the Institute, Head of the Laboratory of Chemical Materials Science, Institute of Solid State Chemistry and Mechanochemistry of the Siberian Branch of the RAS, Novosibirsk, Russian Federation, This email address is being protected from spambots. You need JavaScript enabled to view it.">This email address is being protected from spambots. You need JavaScript enabled to view it.
In the section MATERIALS SCIENCE IN MECHANICAL ENGINEERING
Year 2024
Issue 1(66)
Pages 71–79
Type of article RAR
Index UDK 621.762.2
DOI https://doi.org/10.46864/1995-0470-2024-1-66-71-79
Abstract The article considers the mechanochemical preparation of TiC-Ni composites in reaction mixtures of Ti-C-Ni powders and the formation of the structure of materials during their sintering under pressure. The synthesis was carried out in an AGO-2 planetary ball mill with a mixture processing time of 12 and 20 min; their subsequent sintering was performed at a temperature of 950 °C and a pressure of 130 MPa. The results of diffraction studies are presented for structural-phase transformations in mixtures of equimolar composition of titanium and carbon depending on the nickel content in the range of 50–70 wt.%. It is established that an increase in the Ni concentration leads to a decrease in the size of the formed TiCx crystallites from 29 ± 1 to 16 ± 1 nm. A high carbon content TiC0.88–0.98 carbide is formed in Ti-C-(50 and 60 %)Ni compositions and non-stoichiometric TiC0.62–0.78 at 70 % Ni. The microstructure of dispersion-strengthened grains of the nickel solid solution is formed during sintering of TiC/(50–60 %)Ni mechanocomposites. Titanium carbide inclusions have a spherical shape and a diameter of 60–100 nm. When sintering TiC/70%Ni, depleted titanium carbide has a grain boundary distribution with the formation of large (~400 nm) agglomerates. The microhardness of sintered materials is in the range of 850–900 HV.
Keywords mechanocomposites, titanium carbide, nickel, mechanochemical synthesis, mechanostimulated reactions, metal matrix composite, dispersion-hardened structure
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